It will be competing with 62 other songs from eligible feature-length motion pictures for nomination, which will be announced Feb 2.
"Na na" was penned by double Oscar winner Rahman, Blaaze and Vivian Chaix and crooned by Rahman, Blaaze, Chaix, A. R. Ameen (Rahman's son), Clinton and Dominic.
Directed by Emmy nominated Peter Billingsley, "Couples Retreat" stars MTV winner Vince Vaughn, Jason Bateman and Kristin Davis. It revolves around four couples who go to a tropical-island resort for a vacation.
The 82nd Academy Awards presentation will take place March 7 in Hollywood, California.